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Ideal gas model

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Topic updated on 10/13/2020 12:09pm

The temperature, pressure, volume and the amount (moles) of substance of a gas are the factors that affect the behaviour of a gas.The ideal gas equation can be described as a relationship of the above four variables regarding a gas.

PV = nRT                                        The constant R = 8.314 J K-1 mol-1                                                                • Any gas which obeys the above relationship under any given temperature and pressure is referred as an ideal gas.

Derivation of Boyle law from the ideal gas equation PV= nRT

For a fixed mass of gas at constant temperature the product nT is constant. As R is constant                           nRT = k (a constant)

  PV = k

That is the pressure of a fixed mass of gas at constant temperature is inversely proportional to the volume of the gas (Boyle Law).

Derivation of Charles law from the ideal gas equation

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Derivation of Avogadro’s law from the ideal gas equation

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• Molar volume

The molar volume of a gas is the volume of one mole of gas. Molar volume of a gas varies with temperature and pressure. Volume of one mole of a gas at 0 °C and 1 atm is defined as the molar volume of a gas at standard temperature and pressure.

Alternative forms of ideal gas equation

PV = nRT

PV = (w/M)RT

PM = (w/V) RT                                                                                                                                                             PM = dRT                     where d- density

P = (n/V)RT                                                                                                                                                                   P = cRT

 

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